Jet fuel cleanup relies on laundry detergent booster

Draining jet fuel from Navy planes, known as defueling, was a routine step before doing maintenance work on the planes.  This defueling process at Alameda Point inadvertently contaminated groundwater at one location across the street from the Pottery Barn Outlet on West Oriskany Avenue.  During February, the Navy’s cleanup contractor conducted a form of industrial-scale in-ground chemotherapy known as oxidation. 

The injected chemical compound breaks apart the fuel molecules, turning them into harmless carbon dioxide, water, and oxygen.  The main ingredient in this oxidation process is sodium percarbonate, the same active ingredient in OxyClean™ laundry whitener and stain remover, albeit with a different objective.

Continue reading “Jet fuel cleanup relies on laundry detergent booster”

Navy digs up petroleum contamination in rare cleanup action

Cleaning up petroleum contamination in soil and groundwater is pretty straightforward.  It is usually accomplished by one or more tried-and-proven methods that rely on inserting PVC pipe into the contamination zone for treatment.  But multiple efforts outside the sprawling Building 5 hangar complex on West Tower Avenue at Alameda Point failed to reduce contamination to regulatory goals.  In August 2020, after almost two decades of investigation and treatment efforts, the Navy resorted to a rarely used option of digging up all of the soil down to the water table and hauling most of it away.

Building 5 was the location of the Navy’s plane refurbishing and overhaul facility where thousands of civilians worked.  It was known as the Naval Air Rework Facility.  Before an airplane was moved into the hangar, it underwent de-fueling, flushing out fuel lines and cleaning various components with products akin to paint thinner.  This preparatory work was the source of the contamination in the soil and groundwater near the big hangar doors. Continue reading “Navy digs up petroleum contamination in rare cleanup action”

Navy cleans long-gone gas stations

The Navy has spent more than 15 years cleaning up contaminated groundwater underneath two former gas station sites at Alameda Point. They are still at it, but it’s not because the Navy is slow or lacking in commitment and expertise. It’s the nature of groundwater cleanup, which involves intermittent treatment efforts.

In July, the Navy’s contractor returned to the old gas station and car wash site on West Pacific Avenue at Main Street and to the old commissary gas station site at West Tower Avenue and Main Street across from Bayport. It’s the third visit to these sites to eliminate petroleum hydrocarbon contamination in groundwater, in addition to earlier removal of underground tanks, fuel lines, and soil. The contaminants are located from 2 to 16 feet below ground surface.

Workers at the old gas station and car wash site on West Pacific Avenue on July 13, 2015 preparing to inject cleanup solutions into the ground. The Navy operated a gas station and car wash on the site from 1971 to 1980. Green tank on truck contains non-potable water for on-site mixing of treatment solution. Soccer field is in the background.
Workers at the old gas station and car wash site on West Pacific Avenue on July 13, 2015 preparing to inject cleanup solutions into the ground. The Navy operated a gas station and car wash on the site from 1971 to 1980. Green tank on truck contains non-potable water for on-site mixing of treatment solution. Soccer field is in the background.

The goal is to bring the property up to the public health and environmental standards required for the future commercial and residential uses previously determined by the city.

“When groundwater contamination is involved, such as at the two former gas stations, cleanups often involve multiple phases, each building upon earlier accomplishments,” said Dr. Peter Russell, who has been reviewing Navy cleanup plans and preparing cleanup-related documents on behalf of, and at the direction of, the city since 1997. “As long as all imminent health and environmental risks are eliminated early on, often the most cost-effective approach to complete remediation is incremental,” explained Russell. “In contrast, a massive initial remedial effort that is sure to achieve all remedial goals in one pass would likely involve over-sizing the treatment system, which is more disruptive and expensive than a phased approach.”

During previous cleanup visits, the Navy used a vapor extraction system to remove the bulk of the petroleum contamination. The process involves pumping air into numerous pipes, called wells, which extend into the water-saturated zone where the contamination is. The air pressure creates vapor that is part air, part water and part petroleum. The vapor is then sucked out through another set of wells, and the petroleum vapors are captured in drums of granulated charcoal, while the water is shunted off to a separate container.

Air injection/extraction system operating at W. Pacific Avenue gas station site in 2013 and 2014. System extracts and captures petroleum vapors.
Air injection/extraction system operating at W. Pacific Avenue gas station site in 2013 and 2014. System extracts and captures petroleum vapors.

The method of blowing bubbles in mud and sucking out the air sounds unsophisticated, but it works. After running the system in 2013 and 2014 at the West Pacific Avenue gas station site, for example, the level of one contaminant, benzene, went from around 1,000 micrograms per liter down to 58, bringing the contamination low enough to allow indigenous bacteria to finish the job.

Air injection and vapor extraction system operating at former commissary gas station site in May 2013. Charcoal tank to capture vapors is at left.
Air injection and vapor extraction system operating at former commissary gas station site in May 2013. Charcoal tank to capture vapors is at left.

The Navy returned to these sites in July and, in this phase, they came to help natural bacteria finish up the job.   Allowing bacteria to clean up petro chemicals through natural digestion is called bioremediation. To be effective and not take a century to eliminate the problem, the bulk of the chemicals need to first be reduced to concentrations that do not overwhelm the bacteria.

At both gas station sites the Navy used a special product designed to foster growth of natural bacteria in the ground, which includes a form of time-release peroxide that turns into oxygen over a period of 12 months. An oxygen environment is necessary for the bacteria to digest petroleum. The bacteria utilize the hydrocarbons (hydrogen and carbon) in the petroleum chemicals as part of their metabolic processes and convert them into carbon dioxide, water, and microbial cell mass. Water samples will be taken at three, six, and nine months after the July injections to evaluate effectiveness.

“The Navy’s gas station remedial program is comparable to the private sector gas station cleanup program,” said Yemia Hashimoto, Engineering Geologist with the San Francisco Bay Water Board. “The cleanup requirements are similar and the required timelines for project completion are similar.” The Water Board is a California state agency and is the lead regulatory agency overseeing the Navy’s petroleum cleanup program.

The other type of groundwater contamination encountered at Alameda Point comes from a chlorinated solvent used in cleaning aircraft parts. Unlike lighter-than-water petroleum products, chlorinated solvents can sink through the upper water zone to a depth of 30 feet or more and complicate cleanup. But solvent cleanup still relies on a phased cleanup approach, often employing bacteria in the final phase.

Originally published in the Alameda Sun.

Complete background and a detailed description of the cleanup process at the two gas station sites is in the Bioremediation Work Plan issued in July 2015.

Fuel contamination in groundwater flagged for more cleanup work

Under the petroleum cleanup program the Navy has been removing tanks and fuel lines and cleaning up spills and fuel leaks dating back to the early 1990s before the base closed.  Most of the tanks and fuel lines were removed within three years after the base closed in 1997. 

Cleaning up leaked and spilled fuel has been slower, often involving running a vapor extraction pump 24/7 for years.  In a few cases, a groundwater contamination site will require a callback after the initial work is completed.  The Navy’s routine monitoring of groundwater, even after cleanup work has been completed, is aimed at determining whether there is a rebound in contamination readings and follow-up treatment is necessary.  Three such sites needing more work, on land recently acquired by the city, are currently undergoing follow-up treatment at the Navy’s expense.

Two of the sites once served as automobile service stations.  The other site is where fuel was removed from planes before they were serviced. 

Former location of auto service station and car wash where fuel leaked into the ground.  Part of the site is receiving follow-up cleanup work.  Near Main St. and Pacific.  Soccer field in background.
Former location of gasoline service station and car wash operated between 1971 and 1980 where fuel leaked into the ground. Part of the site is receiving follow-up cleanup work. Near intersection of Main St. and Pacific. Soccer field in background.

The treatment method is simple.  Air is pumped into the ground where the contamination is the highest.  This causes the petroleum products to vaporize, and then a suction system draws out the vapors into a barrel of charcoal.  The air injected into the ground also helps natural petroleum-digesting bacteria to grow.

Petroleum cleanup site receiving follow-up cleanup next to Main St. across from Bayport.  Site was former location of Navy auto service station.
Petroleum cleanup site receiving follow-up cleanup next to Main St. across from Bayport. Site was former location of Navy auto service station.

Solar-powered cleanup for the first time at Alameda Point  

Air injection/extraction pumps at the two former service station sites are running on electricity from the grid.  At the former plane de-fueling site next to Building 410, however, the Navy is using a solar-powered pump for the first time anywhere at Alameda Point.  Derek Robinson, the Navy’s Environmental Coordinator, explained the solar choice saying, “Electricity is not optimum because the overhead electrical tie-in is located too far away for the system to be tied in to the grid cost effectively.  The solar units provide the power necessary to operate the air sparging and soil vapor extraction system at a competitive price.”  The only other option was a combustion engine pump running on gas or diesel.  

“The battery storage system is traditional lead/acid batteries,” said Robinson.  “The solar array charges storage batteries allowing the system to store energy and operate in cloud cover and beyond strictly daylight hours; however, the system is designed to power off the blowers once the voltages drop below a preset level,” he said.  

Sustainable Technologies, located just a block away at Alameda Point, constructed the entire rig.  It consists of solar panels, a box full of lead-acid batteries, a circuit panel, and a pump.  Ironically, Sustainable Technologies is located on a Superfund site that will take another six years to clean up.  

Solar-powered cleanup at Building 410.
Solar-powered cleanup at Building 410.

The area next to Building 410 where the fuel spills occurred has had a number of cleanup actions going back to 2002.  “Corrective actions under the petroleum program were conducted in 2002 and 2011 and a remedial action under the CERCLA [Superfund] program was conducted between 2005 and 2006,” said Robinson.

Work will continue until the end of the year.  The Navy will always be responsible for returning to do more cleanup work if groundwater testing shows some of the contamination was missed.

Locations of three petroleum cleanup sites currently undergoing more cleanup work.


Cleanup at future Town Center – Alameda Point East Gate area

The city has announced that over 500 acres of land will be transferred from the Navy to the city on June 4, 2013.  It will be the first – and largest – of a four-phase schedule of land transfers to the city.  One of the areas that won’t be transferred this year is located at the main entryway into the future Town Center currently being designed.

OU-2B cleanup area
Illustrations on map by Richard Bangert. Click on map to enlarge.

Driving into the “East Gate” on West Atlantic Avenue to Ferry Point Road at the Seaplane Lagoon takes you through part of the future Town Center – and through a major environmental cleanup area called Operating Unit (OU) 2B.

Town Center close-upPlans for a vibrant mixed-use Town Center to kick off redevelopment are now in the design stage, but 33 acres on the south side of West Atlantic Avenue won’t be transferred to the city until 2019.  That’s when contaminated groundwater is expected to be cleaned up to commercial standards, allowing the Navy to turn over the land.

The overhaul of aircraft and ship engines in this area led to major contamination of groundwater with trichloroethane and vinyl chloride, as well as pockets of soil contamination.  After testing various cleanup methods on the contaminated groundwater area – called a plume – the Navy and regulatory agencies have decided to rely mainly on bioremediation – natural bacteria – to degrade the contamination. 

Soil hot spots will be removed, except under buildings.  Future developers will be responsible for soil under buildings once they are demolished.

One of the groundwater hot spots close to the Seaplane Lagoon was successfully treated last year with a heat and vapor extraction system.  Some of the other hot spots are impossible to treat with electrical heating because of underground power lines nearby.

UO-2B plume map w:photo overlay
Click on image to enlarge

The Navy has found bioremediation to be the most practical method to finish the job.  Work details will be finalized later this year.  Bioremediation can involve injecting new bacteria, but here it will likely mean injecting oxygen to spur the growth of existing bacteria.  It’s the carbon atoms in the chemical contaminants that are attractive to bacteria, allowing them to naturally disassemble a chemical compound.

Someday, decades from now, the danger from vapors entering buildings will be low enough to permit ground floor residential use.  Current restrictions imposed under the Navy’s cleanup plan will prohibit ground floor residential, but will allow residential use above the first floor, provided an approved vapor barrier and venting system is installed under any new construction.  First floors will be allowed to have commercial uses once the city receives the land in 2019.  Groundwater monitoring wells around the cleanup area will remain usable and accessible for regular monitoring for at least 20 years.

The cleanup area north of West Atlantic – 13 acres called Site 3 – will be turned over to the city next year following removal of several contaminated soil hot spots containing lead and other contaminants.  Some of the contaminated soil areas are under building slabs on Site 3 and will be the responsibility of a future developer.  All of the buildings in the East Gate cleanup area called Operating Unit (OU) 2B – 46 acres – are expected to be demolished rather than reused.

Site 3 north of West Atlantic was also heavily contaminated with jet fuel around an area where underground fuel storage tanks were once located.  The former storage tank area is west of the jet monument and is still dotted with white pipe stubs once connected to a maze of cleanup pipes.  The jet fuel cleanup was completed two years ago under the Navy’s Petroleum Program using a vapor extraction system.  Removal of underground tanks and fuel lines was completed in 1999.

Vapor extraction system that operated for several years to clean up jet fuel in the ground on Site 3.
Vapor extraction system that operated for several years to clean up jet fuel in the ground on Site 3. Charcoal filter tank has been removed. Jet monument and Building 360 are in the background.

OU-2B looking east toward Bldg 360
Click on image to enlarge.

Jet at East Gate w OU-2B

Removing jet fuel line in OU-2B cleanup area in 1999.  Jet monument is in background.
Removing jet fuel line in OU-2B cleanup area in 1999. Jet monument is in background. Source: Navy environmental newsletter, Winter 1999.

Navy’s Proposed Cleanup Plan for OU-2B.

Berkeley Lab Site Environmental Plan Released

Looking toward Berkeley Lab site.

Conceptual buildout for Lab 2nd campus

The Site Management Plan (SMP) for the proposed site of the Berkeley Lab Second Campus at Alameda Point was finalized on November 18.  Prepared by the city’s longtime environmental consultant, and signed off on by the Navy and regulatory agencies, the document was prepared in order to mitigate potential risks associated with development of the 45-acre parcel near the ship docks. Its primary purpose is to provide direction to construction contractors and workers so that their digging, dewatering, and soil handling activities do not jeopardize the environment or the health of the surrounding community.

Crash Course on Cleanup

The document offers a crash course on the 20-plus years of environmental cleanup of the area, including areas that barely intersect the Site on the margins.  Even if the area were never to have been polluted by Navy activities, the SMP would still be required because of a decade-old city ordinance governing digging into a subsurface layer called the Marsh Crust that contains petroleum-related pollution.

What is the Marsh Crust?

Before 1900, the areas now occupied by Alameda Point and Bayport were tidal marshlands. In the late 1800s and early 1900s, before the health effects of industrial pollution were known, two industries nearby dumped their waste into the water. One of those industries was a coal gasification plant in Oakland.  The other was the Pacific

Alameda in 1915

Coast Oil Refinery located at what was then the tip of Alameda, not far from Encinal High School. Much of the petroleum-related waste, classified as polynuclear aromatic hydrocarbons (PAHs), settled in the marsh.  Between 1900 and 1940, these marshlands were filled with dredge material to create more land.

PAH contamination created the “marsh crust” layer at four to fifteen feet below ground surface, which is a thin layer of PAHs and oil believed to come from historical waste discharges prior to infill.

No one was concerned about this marsh crust caused by former private industrial activity until the Navy decided to close down the base.

Underground testing

By the time the Navy was ready to close down the base, including the area that is now Bayport and the future Alameda Landing, soil boring and groundwater testing was routine.  Underground tests in the late 1990s are what led to the Remedial Action Plan and Record of Decision that were signed in 2000.  (If these documents were drafted today, they would probably have the term “carbon sequestration” in them because this carbon waste is best left where it is – sequestered in the earth.)

Those two documents led to the creation of Alameda’s “permit-before-you-dig” Marsh Crust Ordinance.  The city’s ordinance requires a permit only for digging projects that dig deep enough to potentially encounter the marsh crust — that is, for digging deeper than the threshold depth.  The ordinance is in place so that excavated soil containing petroleum-related waste is properly handled.  The Marsh Crust extends from the Bayport/Main Street area about halfway out onto the Point at 4 to 15 foot depths.  A significant portion of the proposed Lab site (see maps below) does not have any Marsh Crust underneath.

Cleanup of Navy contamination at Site in final stages

Some work, including groundwater remediation, is in the final stages.  And some groundwater is past the active remediation stage and now in the stage during which contaminants will be degraded by natural processes.

The land will be cleaned to commercial standards ahead of the Lab’s timeline for occupancy. If any digging, trenching or excavating encounters a treatment zone, then more stringent handling procedures and protocols would come into play.

It will be the duty of the contractors to develop a site-specific Health and Safety Plan for their workers based on the disclosures in the Site Management Plan.  These health and safety plans have to be submitted to the Navy and regulatory agencies for review.

The Protocols

The SMP describes the protocols for handling soils from the Marsh Crust, such as dust and erosion control.  The SMP includes protocols for dewatering excavated soil, handling of asbestos and lead-based paint during building demolition, and an air monitoring system.  In certain areas, vapor intrusion measures will be required, which could include a vapor barrier, passive venting systems under slabs, and podium-level (partially above-ground) garages with natural venting.

Paint stripping building (Building 410) with white cleanup pipe stubs in ground.  Active cleanup completed.  Looking northwest.

Navy’s Environmental Investigations

The Navy began comprehensive investigations of the area being offered to the Lab starting in the late 1980s.  They analyzed for metals, petroleum-related compounds, PCBs, pesticides, chemicals that evaporate, and a form of hydrocarbon called PAHs (polycyclic aromatic hydrocarbons.)  More than a dozen above ground storage tanks containing paint stripping chemicals and fuel were removed from the area.  Underground fuel storage tanks from an adjacent area were excavated.  Soil has been excavated.  Leaked jet and diesel fuel has been removed using vapor extraction, chemical neutralizers, and bioremediation.  Monitoring wells and former injection/extraction wells (evident as PVC stubs in the ground) dot the area.

Concerted Cleanup Effort

Considering the contamination history, the concerted cleanup effort over the past two decades, starting before the EPA became involved, has come a long way.  The suitability of the site for commercial or residential uses has been, or will be, satisfied by the remediation programs under the Comprehensive Environmental Response and Liability Act (CERCLA) and the Petroleum Program.  Furthermore, when discounting the fact that no groundwater would ever be used for drinking water, the site would meet the even higher unrestricted residential use standard much sooner.

Alameda’s Proposal for Berkeley Lab 2nd Campus at Alameda Point

Site Management Plan for proposed Berkeley Lab 2nd Campus at Alameda Point

Berkeley Lab parcel at Alameda Point. Top of outline area designated for first phase of Lab buildout; red area is for second phase.

City of Alameda Marsh Crust Page

Marsh Crust Map - Four irregular outlines emanating from right side indicate various depths.

Video: Alameda Point 2011 Cleanup Update

Dr. Peter Russell, the city’s environmental consultant, made a presentation to the Alameda Reuse and Redevelopment Authority on November 2, 2011, updating them on the status of cleanup at Alameda Point.

This video is an edited version with added images.

(Note:  The phrase “closed site” used in the presentation does not mean off limits.  It means active cleanup is finished.)